By Mohammed Muzibur Rahman and Abdullah Mohamed Asiri
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Colloids Surf B 2016;141:44–52.  Klaewklod A, Tantishaiyakul V, Hirun N, Sangfai T, Li L. Characterization of supramolecular gels based on β-cyclodextrin and polyethyleneglycol and their potential use for topical drug delivery. Mater Sci Eng-C 2015;50:242–250.  Lin Y, Li L, Li G. A new supramolecular gel via host–guest complexation with cucurbituril and N-(4-diethylaminobenzyl)chitosan. Carbohydr Polym 2013;92(1):429– 434.  Yang Y, Chen X, Huang D, Ye W. Supramolecular gel based on the cyclodextrin inclusion assembly of Ag-Fe3O4 nanodimers and Pluronic F127.
Physical Review Letters. 2003;91:224501. 224501.  Anachkov S, Danov K, Basheva E, Kralchevsky P, Ananthapadmanabhan K. Determination of the aggregation number and charge of ionic surfactant micelles from the stepwise thinning of foam films. Advances in Colloid and Interface Science. 2012;183–184:55-67. 003.  Tuinier R, Rieger J, de Kruif C. Depletion-induced phase separation in colloid-polymer mixtures. Advances in Colloid and Interface Science. 2003;103:1-31. 1016/S00018686(02)00081-7.
A reasonable model was proposed to explain the novel phase transition process, as shown in Figure 10. When the ligand m-NpSB was spread on water surface, a smooth plain film was formed, which had also been verified by the AFM and XRD data. With the increment of surface pressure near the transition point, due to the spatial hindrance and lower energy level induced by the molecular rigidity and size, some molecules changed their conformational alignment and became more declined to surface, which could be well monitored by the AFM measurement at different surface pressures.